Terpene synthases catalyze the cleavage and formation of highly complex multiple bonds via a series of carbocation intermediates to create a significant diversity of terpene molecular skeletons. 1 ...

The polysaccharide β-1,2-glucan consists of repeating units of glucose linked together by β-1,2-glycosidic bonds. Cyclic β-1,2-glucans (CβGs) occur in different bacterial species and have a role in ...

The Diels-Alder reaction, a widely used transformation in organic synthesis, forms six-membered rings from a conjugated diene and a dienophile-frequently an alkene. Usually, these two reactants must ...

SOME MARINE organisms have a knack for making steroidal compounds containing halogens. Chemists have long tried to do the same thing, because such compounds can be useful, for example, in treating ...